"I distrust those people who know so well what God wants them to do because I notice it always coincides with their own desires."- Susan B. Anthony"

- Dwayne

Limiting ourselves again to one spatial dimension, we write the time independent Schrödinger equation in this form:

Since this equation contains no complex numbers except possibly ψ itself, it has real solutions, and these are the ones in which we are interested. You will notice that if V > E, then A is positive and ψ(x) has the same sign as its second derivative. This means that the graph of ψ(x) curves upward above the x axis and downward below it. Thus it cannot cross the axis. On the other hand, if V < E, then A is negative and ψ(x) and its second derivative have opposite signs. In this case the graph of ψ(x) curves downward above the x axis and upward below it. As a result, the graph of ψ(x) keeps crossing the axis — it is a wave. Moreover, the larger the difference E − V, the larger the curvature of the graph; and the larger the curvature, the smaller the wavelength. In particle terms, the higher the kinetic energy, the higher the momentum.

Let us now find the solutions that describe a particle "trapped" in a potential well — a bound state. Consider this potential:

Observe, to begin with, that at x1 and x2, where E = V, the slope of ψ(x) does not change since d2ψ(x) / dx2 = 0 at these points. This tells us that the probability of finding the particle cannot suddenly drop to zero at these points. It will therefore be possible to find the particle to the left of x1 or to the right of x2, where classically it could not be. (A classical particle would oscillates back and forth between these points.)

Next, take into account that the probability distributions defined by ψ(x) must be normalizable. For the graph of ψ(x) this means that it must approach the x axis asymptotically as

Suppose that we have a normalized solution for a particular value E. If we increase or decrease the value of E, the curvature of the graph of ψ(x) between x1 and x2 increases or decreases. A small increase or decrease won't give us another solution: ψ(x) won't vanish...

Since this equation contains no complex numbers except possibly ψ itself, it has real solutions, and these are the ones in which we are interested. You will notice that if V > E, then A is positive and ψ(x) has the same sign as its second derivative. This means that the graph of ψ(x) curves upward above the x axis and downward below it. Thus it cannot cross the axis. On the other hand, if V < E, then A is negative and ψ(x) and its second derivative have opposite signs. In this case the graph of ψ(x) curves downward above the x axis and upward below it. As a result, the graph of ψ(x) keeps crossing the axis — it is a wave. Moreover, the larger the difference E − V, the larger the curvature of the graph; and the larger the curvature, the smaller the wavelength. In particle terms, the higher the kinetic energy, the higher the momentum.

Let us now find the solutions that describe a particle "trapped" in a potential well — a bound state. Consider this potential:

Observe, to begin with, that at x1 and x2, where E = V, the slope of ψ(x) does not change since d2ψ(x) / dx2 = 0 at these points. This tells us that the probability of finding the particle cannot suddenly drop to zero at these points. It will therefore be possible to find the particle to the left of x1 or to the right of x2, where classically it could not be. (A classical particle would oscillates back and forth between these points.)

Next, take into account that the probability distributions defined by ψ(x) must be normalizable. For the graph of ψ(x) this means that it must approach the x axis asymptotically as

Suppose that we have a normalized solution for a particular value E. If we increase or decrease the value of E, the curvature of the graph of ψ(x) between x1 and x2 increases or decreases. A small increase or decrease won't give us another solution: ψ(x) won't vanish...

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